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Reactive Intermediates III: Free Radicals, Carbenes, Arynes and NitrenesĬhapter 14.
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Synthetic Reactions III: Synthetic Reactions of Carbon Nucleophiles, Part 1ġ2.1 Carbon-Carbon Bond Formation: Carbon Nucleophiles and Electrophilesġ2.2 Substitution and Addition With Metal Alkyl Reagents Having C-M ? Bondsġ2.3 Metal Enolates: Versatile Carbon Nucleophilesġ2.5 Conjugate Addition of Enolates and Similar Compoundsġ2.6 Azaenol Derivatives: Imines, Hydrazones and EnaminesĬhapter 13.
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Reactive Intermediates II: Carbanions and Their Reactivityġ1.1 Carbanions: Introduction and Overviewġ1.3 Carbanions Stabilized by HeteroatomsĬhapter 12. Synthetic Reactions II: Using Carbocations for C-C Bond Formation in Synthesisġ0.4 Addition of Stabilized Cations to Alkenes: The Prins, Mannich, and Mukaiyama ReactionsĬhapter 11. Reactive Intermediates I: CarbocationsĬhapter 10.
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Physical Organic Chemistry and Reaction MechanismsĨ.4 Activation Parameters from Kinetic StudiesĨ.5 Correlating Similar Reactions: Linear Free Energy RelationshipsĨ.8 The Variable Transition State and the Concept of the Mechanistic SpectrumĨ.9 Using Regiochemistry and StereochemistryĨ.10 The Reactivity-Selectivity PrincipleĬhapter 9. The History and Mythology of BenzeneĬhapter 8. Synthetic Reactions I: Pericyclic Reactions and Conservation of Orbital SymmetryĦ.2 Molecular Orbitals of Conjugated Systems Orbital SymmetryĦ.3 Qualitative Perturbation Theory: Approximating Frontier Orbitals of Substituted Alkenes and DienesĦ.7 Combining Pericyclic Reactions in Sequenceħ.2 Aromaticity and Antiaromaticity: The H:uckel Molecular Orbital Model of Cyclic Polyenesħ.3 How Does One Measure Aromaticity? Criteria for Aromaticity and its Quantificationħ.6 The Rest of the Story. Frontier Orbitals and Chemical Reactionsĥ.1 Using Frontier Orbitals (FMOs) to Categorize Reactions and Reagentsĥ.2 Categorizing Reactions Using FMP PairingsĬhapter 6. Organic Short-hand: Acronyms and Name Reactionsģ.1 Organic Synthesis: A Brief Introductionģ.2 Name Reactions: A Historical OverviewĤ.2 Atomic Orbitals: The History of the Modern Atomic ModelĤ.3 Covalent Bonding and Molecular OrbitalsĤ.4 Chemical Reactions: Frontier OrbitalsĬhapter 5. The Fundamentals Revisited: Structure, Bonding, and Reactivityġ.2 Proton Transfers Revisited: Acids and Basesġ.3 Reactions and Reaction Mechanisms: "Electron Pushing"Ģ.5 An Introduction to Asymmetric Synthesis: Asymmetric InductionĢ.6 How Well Did It Go? Measuring Enantiomer RatiosĢ.7 Chirality at Atoms Other Than Carbon: Inversion of Pyramidal CentersĬhapter 3. Literature * Numerous in-chapter worked problems and end-of-chapter additional exercises allow students to apply concepts as they learn them * More than 2500 references to the primary literature in the body of the book(along with another 750 references in the problems) encourage students to become familiar with real scholarship as they master the concepts * Brief historical vignettes about relevant chemists reinforce a historical and humanizing approach to learning scienceĬhapter 1. FEATURES * Uses a unique method of categorizing organic reactions that is based on reactivity principles rather than mechanism or functional group, enabling students to see reactivity patterns in superficially widely disparate systems * Emphasizes fundamental physical organic concepts that reinforce themes, giving students the foundation to understand both mechanisms and synthesis * Covers asymmetric methodologies, a topic that is now ubiquitous in the current In contrast with many other books, this volume is a true textbook, not a reference book. Written by a master teacher, Advanced Organic Chemistry presents a clear, concise, and complete overview of the subject that is ideal for both advanced undergraduate and graduate courses.